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Title:
Full shell coating or cation exchange enhances luminescence | Nature Communications
Description:
Core-shell structure is routinely used for enhancing luminescence of optical nanoparticles, where the luminescent core is passivated by an inert shell. It has been intuitively accepted that the luminescence would gradually enhance with the coverage of inert shell. Here we report an “off-on” effect at the interface of core-shell upconversion nanoparticles, i.e., regardless of the shell coverage, the luminescence is not much enhanced unless the core is completely encapsulated. This effect indicates that full shell coating on the luminescent core is critical to significantly enhance luminescence, which is usually neglected. Inspired by this observation, a cation exchange approach is used to block the energy transfer between core nanoparticle and surface quenchers. We find that the luminescent core exhibits enhanced luminescence after cation exchange creates an effective shell region. These findings are believed to provide a better understanding of the interfacial energy dynamics and subsequent luminescence changes. Core-shell designs enhance the luminescence of lanthanide-doped upconversion nanoparticles (UCNPs), but the effect of shell coverage was insufficiently characterized. Here the authors demonstrate, on a series of core-shell UCNPs with various shell coverage ratios, an on-off effect by which luminescence is enhanced only when a full coverage is achieved.
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shell, nanoparticles, luminescence, surface, upconversion, naerf, article, core, fig, coreshell, energy, cas, google, scholar, nayf, emission, protection, ucnps, quenching, janus, supplementary, ions, coverage, intensity, pubmed, solution, luminescent, nature, inert, naerfsionayf, full, exchange, nanoparticle, excitation, sio, chem, zhang, process, naerfy, nanocrystals, thickness, transfer, time, green, enhancement, defects, quenchers, light, etching, red,
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nature portfolio innovative research team privacy policy er/nayf4/silica core/shell/shell nanoparticles energy-dispersive x-ray spectroscopy advertising refractive index nature social media x-ray photoelectron spectroscopy multi-layer core-shell nanoparticles reprints er/nayf4 core/shell nanocrystals naerf4/sio2 janus nanoparticles naerf4/sio2 janus nanoparticle β-nalnf4 nanocrystals induced lanthanide-doped upconversion nanoparticles colloidal lanthanide-doped nanocrystals upconverting long-wavelength radiation flexi‐pegda upconversion implant broadband dye-sensitized upconversion anhydrous rare-earth acetates core-shell lanthanide nanoparticles multi-shell upconverting nanocrystals including dye-sensitization strategy16 high-level local universities pre-synthesized naerf4 nanoparticles core-multi-shell nanoparticles ce3+-doped garnet phosphors core-shell upconversion nanoparticles small-sized upconversion nanoparticles constructing core-shell structures monodispersed β-naerf4 ucnps prepare core-shell ucnps quantum yields x-ray diffraction additional experimental details cation inter-diffusion occurs eds line-scan profile size-dependent luminescence dual surface hydrophobicity/hydrophilicity low-doped luminescent core surface-involved energy transfer high quantum yield china permissions core-multi-shell design vivo photodynamic therapy figure 4c compares step-wise surface passivation
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headline:Full shell coating or cation exchange enhances luminescence
description:Core-shell structure is routinely used for enhancing luminescence of optical nanoparticles, where the luminescent core is passivated by an inert shell. It has been intuitively accepted that the luminescence would gradually enhance with the coverage of inert shell. Here we report an âoff-onâ effect at the interface of core-shell upconversion nanoparticles, i.e., regardless of the shell coverage, the luminescence is not much enhanced unless the core is completely encapsulated. This effect indicates that full shell coating on the luminescent core is critical to significantly enhance luminescence, which is usually neglected. Inspired by this observation, a cation exchange approach is used to block the energy transfer between core nanoparticle and surface quenchers. We find that the luminescent core exhibits enhanced luminescence after cation exchange creates an effective shell region. These findings are believed to provide a better understanding of the interfacial energy dynamics and subsequent luminescence changes. Core-shell designs enhance the luminescence of lanthanide-doped upconversion nanoparticles (UCNPs), but the effect of shell coverage was insufficiently characterized. Here the authors demonstrate, on a series of core-shell UCNPs with various shell coverage ratios, an on-off effect by which luminescence is enhanced only when a full coverage is achieved.
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headline:Full shell coating or cation exchange enhances luminescence
description:Core-shell structure is routinely used for enhancing luminescence of optical nanoparticles, where the luminescent core is passivated by an inert shell. It has been intuitively accepted that the luminescence would gradually enhance with the coverage of inert shell. Here we report an âoff-onâ effect at the interface of core-shell upconversion nanoparticles, i.e., regardless of the shell coverage, the luminescence is not much enhanced unless the core is completely encapsulated. This effect indicates that full shell coating on the luminescent core is critical to significantly enhance luminescence, which is usually neglected. Inspired by this observation, a cation exchange approach is used to block the energy transfer between core nanoparticle and surface quenchers. We find that the luminescent core exhibits enhanced luminescence after cation exchange creates an effective shell region. These findings are believed to provide a better understanding of the interfacial energy dynamics and subsequent luminescence changes. Core-shell designs enhance the luminescence of lanthanide-doped upconversion nanoparticles (UCNPs), but the effect of shell coverage was insufficiently characterized. Here the authors demonstrate, on a series of core-shell UCNPs with various shell coverage ratios, an on-off effect by which luminescence is enhanced only when a full coverage is achieved.
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