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Title:
White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram | Microchimica Acta
Description:
The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
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Keywords {🔍}
article, google, scholar, cas, zhang, chem, wang, liu, detection, upconversion, thiram, whitelight, paper, dots, yang, quantum, acta, visual, mei, test, anal, color, chen, privacy, cookies, content, nanoparticles, colorimetric, sun, jing, energy, emission, access, fluorescent, mater, information, publish, search, emissive, determination, pesticide, shikha, yong, authors, red, white, fluorescence, huang, microchim, zhou,
Topics {✒️}
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headline:White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram
description:The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
datePublished:2019-01-12T00:00:00Z
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Lead-dithizone complex
Energy transfer
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Color-differentiation
Nanochemistry
Nanotechnology
Characterization and Evaluation of Materials
Analytical Chemistry
Microengineering
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description:The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
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