
NATURE . COM {
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Title:
Order enables efficient electron-hole separation at an organic heterojunction with a small energy loss | Nature Communications
Description:
Donor–acceptor organic solar cells often show low open-circuit voltages (V OC) relative to their optical energy gap (E g) that limit power conversion efficiencies to ~12%. This energy loss is partly attributed to the offset between E g and that of intermolecular charge transfer (CT) states at the donor–acceptor interface. Here we study charge generation occurring in PIPCP:PC61BM, a system with a very low driving energy for initial charge separation (E g−E CT ~ 50 meV) and a high internal quantum efficiency (η IQE ~ 80%). We track the strength of the electric field generated between the separating electron-hole pair by following the transient electroabsorption optical response, and find that while localised CT states are formed rapidly (<100 fs) after photoexcitation, free charges are not generated until 5 ps after photogeneration. In PIPCP:PC61BM, electronic disorder is low (Urbach energy <27 meV) and we consider that free charge separation is able to outcompete trap-assisted non-radiative recombination of the CT state. Achieving charge separation in low energy loss organic heterojunctions is crucial to the efficiency of donor-acceptor solar cells, whilst the timescale of the process remains largely unknown. Here, Menke et al. observe slow charge separation up to 5 ps in a system with small energy offset of 50 meV.
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energy, states, charge, separation, article, organic, push, pushinduced, google, scholar, absorption, fig, pipcp, state, cas, nature, blend, pubmed, charges, timescale, pulse, solar, signal, electronhole, cells, offset, urbach, low, pipcppcbm, interface, blends, differential, function, efficient, loss, mev, note, supplementary, separated, electronic, molecular, delay, pumppush, small, electric, field, generated, response, localised, excitons,
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nature portfolio privacy policy pristine pipcp solutions advertising naval research low-offset-energy polymer-fullerene heterojunction disordered nature social media open-circuit voltage bulk-heterojunction solar cells nature quasi-steady-state ea measurements reprints fullerene—electron donor interactions organic donor-acceptor blends n2-filled glove box figure 5b shows previously studied polymer-fullerene polymer solar cells ballistic electron-hole separation organic solar cells higher-lying electronic state separated electron-hole pair probe electron-hole separation high-efficiency organic photovoltaics pump-probe ta spectroscopy separating electron-hole pair diketopyrrolopyrrole-based copolymers reported small-molecule organic photovoltaics direct access initial electron-hole separation high-charge densities generated pump-push-probe capability influence electron-hole separation bound charge-transfer states push-induced response starts push-induced differential ta low-energy loss heterojunctions selected pump-probe delays original author push-induced ta reflects pump-induced ea signal pump-push delay time fullerene organic heterojunctions permissions pump-push-probe ta push-induced charge carriers disorder-free energy gap lower-energy absorption captured energy efficient dissociation
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headline:Order enables efficient electron-hole separation at an organic heterojunction with a small energy loss
description:Donorâacceptor organic solar cells often show low open-circuit voltages (V
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g and that of intermolecular charge transfer (CT) states at the donorâacceptor interface. Here we study charge generation occurring in PIPCP:PC61BM, a system with a very low driving energy for initial charge separation (E
gâE
CTâ~â50âmeV) and a high internal quantum efficiency (η
IQEâ~â80%). We track the strength of the electric field generated between the separating electron-hole pair by following the transient electroabsorption optical response, and find that while localised CT states are formed rapidly (<100âfs) after photoexcitation, free charges are not generated until 5âps after photogeneration. In PIPCP:PC61BM, electronic disorder is low (Urbach energy <27âmeV) and we consider that free charge separation is able to outcompete trap-assisted non-radiative recombination of the CT state. Achieving charge separation in low energy loss organic heterojunctions is crucial to the efficiency of donor-acceptor solar cells, whilst the timescale of the process remains largely unknown. Here, Menke et al. observe slow charge separation up to 5 ps in a system with small energy offset of 50 meV.
datePublished:2018-01-18T00:00:00Z
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Molecular electronics
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Optical spectroscopy
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headline:Order enables efficient electron-hole separation at an organic heterojunction with a small energy loss
description:Donorâacceptor organic solar cells often show low open-circuit voltages (V
OC) relative to their optical energy gap (E
g) that limit power conversion efficiencies to ~12%. This energy loss is partly attributed to the offset between E
g and that of intermolecular charge transfer (CT) states at the donorâacceptor interface. Here we study charge generation occurring in PIPCP:PC61BM, a system with a very low driving energy for initial charge separation (E
gâE
CTâ~â50âmeV) and a high internal quantum efficiency (η
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