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Title:
White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram | Microchimica Acta
Description:
The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
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Keywords {🔍}
article, google, scholar, cas, zhang, chem, wang, liu, detection, upconversion, thiram, whitelight, paper, dots, yang, quantum, acta, visual, mei, test, anal, color, chen, privacy, cookies, content, nanoparticles, colorimetric, sun, jing, energy, emission, access, fluorescent, mater, information, publish, search, emissive, determination, pesticide, shikha, yong, authors, red, white, fluorescence, huang, microchim, zhou,
Topics {✒️}
quantum dot-enzyme-impregnated paper multiple-color upconversion nanoparticles white light-emitting diodes upconversional paper sensor energy migration-mediated upconversion bright white-light upconversion interfacial energy transfer white-light upconversion emission month download article/chapter dithizone-polymeric nanocomposite hybrid concentration-dependent color change swati shikha & yong zhang bright white-light emission single organic compound dithizone complex rare earth micro/nanocrystals multi-shell epitaxial growth post-mortem biological samples white leds lead ions derived paper-based point white-light emission author information authors fluorescent carbon dots related subjects test paper high color rendering test stripe exhibits discernable color change yong zhang full article pdf ratiometric fluorescent chemosensor perovskite quantum dots upconverting optical properties color-discernable detection privacy choices/manage cookies smartphone based visual integrated upconversion nanostructure nanoprobe chitosan-coated cellulose silica gel loaded check access instant access dyes pigments 154 defect state luminescence carbon paste electrodes test stripe european economic area linear signal increase bioresponsive release system
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headline:White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram
description:The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
datePublished:2019-01-12T00:00:00Z
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Upconversional nanoprobe
Lead-dithizone complex
Energy transfer
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Color-differentiation
Nanochemistry
Nanotechnology
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Analytical Chemistry
Microengineering
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headline:White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram
description:The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
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